Defect‐Engineered Metal–Organic Frameworks

Abstract

Defect engineering in metal–organic frameworks (MOFs) is an exciting concept for tailoring material properties, which opens up novel opportunities not only in sorption and catalysis, but also in controlling more challenging physical characteristics such as band gap as well as magnetic and electrical/conductive properties. It is challenging to structurally characterize the inherent or intentionally created defects of various types, and there have so far been few efforts to comprehensively discuss these issues. Based on selected reports spanning the last decades, this Review closes that gap by providing both a concise overview of defects in MOFs, or more broadly coordination network compounds (CNCs), including their classification and characterization, together with the (potential) applications of defective CNCs/MOFs. Moreover, we will highlight important aspects of “defect‐engineering” concepts applied for CNCs, also in comparison with relevant solid materials such as zeolites or COFs. Finally, we discuss the future potential of defect‐engineered CNCs.

Shown for reading. Its publisher allows quoting it, not republishing it.

References 133

1. 1.

   Mittemeijer EJ. Fundamentals of Materials Science, (The Crystal Imperfection; Lattice Defects). 2011;201-244.

   Not in our library

2. 2.

   Capper P. Bulk Crystal Growth in Electronic, Optical and Optoelectronic Materials. 2005.

   Not in our library

3. 3.

   Singh J. Electronic and Optoelectronic Properties of Semiconductor Structures. 2003.

   Not in our library

4. 4.

   Fennell T, Deen PP, Wildes AR, Schmalzl K, Prabhakaran D, Boothroyd AT, Aldus RJ, McMorrow DF, Bramwell ST. Science. 2009;326:415-417.

   Not in our library10.1126/science.1177582

5. 5.

   Božin ES, Malliakas CD, Souvatzis P, Proffen T, Spaldin NA, Kanatzidis MG, Billinge SJL. Science. 2010;330:1660-1663.

   Not in our library10.1126/science.1192759

6. 6.

   Xu GY, Zhong Z, Bing Y, Ye ZG, Shirane G. Nat. Mater. 2006;5:134-140.

   Not in our library10.1038/nmat1560

7. 7.

   Beyerlein RA, Choi-Feng C, Hall JB, Huggins BJ, Ray GJ. Top. Catal. 1997;4:27-42.

   Not in our library

8. 8.

   Bonelli B, Forni L, Aloise A, Nagy JB, Fornasari G, Garrone E, Gedeon A, Giordano G, Trifirò F. Microporous Mesoporous Mater. 2007;101:153-160.

   Not in our library

9. 9.

   Baerlocher C, Xie D, McCusker LB, Hwang S-J, Chan IY, Ong K, Burton AW, Zones SI. Nat. Mater. 2008;7:631-635.

   Not in our library10.1038/nmat2228

10. 10.

    Kitagawa S, Kitaura R, Noro S. Angew. Chem. Int. Ed. 2004;43:2334-2375.

    Not in our library10.1002/anie.200300610

11. 11.

    This reference’s wording can’t be shown under the paper’s licence.

    Not in our library10.1039/c4cs90059f

12. 12.

    Batten SR, Turner DR, Neville MS. Coordination Polymers: Design, Analysis and Application. 2009.

    Not in our library

13. 13.

    Schröder M. Functional Metal-Organic Frameworks: Gas Storage, Separation and Catalysis. 2010.

    Not in our library

14. 14.

    Kreno LE, Leong K, Farha OK, Allendorf M, Van Duyne RP, Hupp JT. Chem. Rev. 2012;112:1105-1125.

    Not in our library10.1021/cr200324t

15. 15.

    Huxford RC, Rocca JD, Lin W. Curr. Opin. Chem. Biol. 2010;14:262-268.

    Not in our library10.1016/j.cbpa.2009.12.012

16. 16.

    Corma A, García H, Llabres i Xamena FX. Chem. Rev. 2010;110:4606-4655.

    Not in our library10.1021/cr9003924

17. 17.

    Ameloot R, Vermoortele F, Hofkens J, De Schryver FC, De Vos DE, Roeffaers MBJ. Angew. Chem. Int. Ed. 2013;52:401-405.

    Not in our library10.1002/anie.201205627

18. 18.

    Choi JS, Son WJ, Kim J, Ahn WS. Microporous Mesoporous Mater. 2008;116:727-731.

    Not in our library

19. 19.

    Wu H, Chua YS, Krungleviciute V, Tyagi M, Chen P, Yildirim T, Zhou W. J. Am. Chem. Soc. 2013;135:10525-10532.

    Not in our library10.1021/ja404514r

20. 20.

    Ravon U, Savonnet M, Aguado S, Domine ME, Janneau E, Farrusseng D. Microporous Mesoporous Mater. 2010;129:319-329.

    Not in our library

21. 21.

    Vermoortele F, Vandichel M, Van de Voorde B, Ameloot R, Waroquier M, Van Speybroeck V, De Vos DE. Angew. Chem. Int. Ed. 2012;51:4887-4890.

    Not in our library10.1002/anie.201108565

22. 22.

    Shearer GC, Chavan S, Ethiraj J, Vitillo JG, Svelle S, Olsbye U, Lamberti C, Bordiga S, Lillerud KP. Chem. Mater. 2014;26:4068-4071.

    Not in our library

23. 23.

    Cliffe MJ, Wan W, Zou X, Chater PA, Kleppe AK, Tucker MG, Wilhelm H, Funnell NP, Coudert F-X, Goodwin AL. Nat. Commun. 2014;5:4176.

    Not in our library10.1038/ncomms5176

24. 24.

    Fang Z, Dürholt JP, Kauer M, Zhang W, Lochenie C, Jee B, Albada B, Metzler-Nolte N, Pöppl A, Weber B, Muhler M, Wang Y, Schmid R, Fischer RA. J. Am. Chem. Soc. 2014;136:9627-9636.

    Not in our library10.1021/ja503218j

25. 25.

    Tsao CS, Yu M-S, Wang C-Y, Liao P-Y, Chen H-L, Jeng U-S, Tzeng Y-R, Chung T-Y, Wu H-C. J. Am. Chem. Soc. 2009;131:1404-1406.

    Not in our library10.1021/ja802741b

26. 26.

    Li YW, Yang RT. J. Am. Chem. Soc. 2006;128:8136-8137.

    Not in our library10.1021/ja061681m

27. 27.

    Park J, Wang ZYU, Sun LB, Chen YP, Zhou HC. J. Am. Chem. Soc. 2012;134:20110-20116.

    Not in our library10.1021/ja3085884

28. 28.

    Marx S, Kleist W, Baiker A. J. Catal. 2011;281:76-87.

    Not in our library

29. 29.

    Cairns AB, Goodwin AL. Chem. Soc. Rev. 2013;42:4881-4893.

    Not in our library10.1039/c3cs35524a

30. 30.

    Foo ML, Matsuda R, Kitagawa S. Chem. Mater. 2014;26:310-322.

    Not in our library

31. 31.

    Burrows AD. CrystEngComm. 2011;13:3623-3642.

    Not in our library

32. 32.

    Yoshida Y, Inoue K, Kurmoo M. Inorg. Chem. 2009;48:267-276.

    Not in our library10.1021/ic801734x

33. 33.

    Takamizawa S, Kohbara MA. Dalton Trans. 2007;3640-3645.

    Not in our library10.1039/b704977c

34. 34.

    Bennett TD, Cheetham AK. Acc. Chem. Res. 2014;47:1555-1562.

    Not in our library10.1021/ar5000314

35. 35.

    Bürgi HB, Weber T. Chimia. 2001;55:510-516.

    Not in our library

36. 36.

    Yang SH, Lin X, Lewis W, Suyetin M, Bichoutskaia E, Parker JE, Tang CC, Allan DR, Rizkallah PJ, Hubberstey P, Champness NR, Thomas KM, Blake AJ, Schröder M. Nat. Mater. 2012;11:710-716.

    Not in our library10.1038/nmat3343

37. 37.

    Choi SB, Furukawa H, Nam HJ, Jung D-Y, Jhon YH, Walton A, Book D, O′Keeffe M, Yaghi OM, Kim J. Angew. Chem. Int. Ed. 2012;51:8791-8795.

    Not in our library10.1002/anie.201202925

38. 38.

    Sánchez-Andújar M, Presedo S, Yáñez-Vilar S, Castro-García S, Shamir J, Señarís-Rodríguez MA. Inorg. Chem. 2010;49:1510-1516.

    Not in our library10.1021/ic901872g

39. 39.

    Fairbank VE, Thompson AL, Cooper RI, Goodwin AL. Phys. Rev. B. 2012;86:144103-144105.

    Not in our library

40. 40.

    Marti-Gastaldo C, Antypov D, Warren JE, Briggs ME, Chater PA, Wiper PV, Miller GJ, Khimyak YZ, Darling GR, Berry G, Rosseinsky MJ. Nat. Chem. 2014;6:343-351.

    Not in our library10.1038/nchem.1871

Cited by papers we hold 9

• Mechanochemically Synthesized Prussian Blue for Efficient Removal of Cesium Ions from Aqueous Solutions · 2022
  Not checked
• Metal-Organic Frameworks: Synthetic Methods and Potential Applications · 2021
  No notice
• Modulated self-assembly of metal–organic frameworks · 2020
  No notice
• Metal–organic framework gels and monoliths · 2020
  No notice
• Multivariate Modulation of the Zr MOF UiO‐66 for Defect‐Controlled Combination Anticancer Drug Delivery · 2020
  No notice
• A coronene-based semiconducting two-dimensional metal-organic framework with ferromagnetic behavior · 2018
  No notice
• Curved crystal morphology, photoreactivity and photosalient behaviour of mononuclear Zn(II) complexes · 2017
  Not checked
• Metal–organic and covalent organic frameworks as single-site catalysts · 2017
  No notice
• Construction of hierarchically porous metal–organic frameworks through linker labilization · 2017
  No notice

Reads

A person counts once a day per paper. We keep no cookie and no address: a reader is a hash that changes every day. Any month under five reads shows no number.