Korelacija rezultata ispitivanja hemijske stabilnosti prirodno i ubrzano starenih baruta / Correlation of chemical stability estimation results of naturally and accelerated aging gun powders

Praćenje sadržaja stabilizatora jedna je od savremenih i pouzdanih metoda koja se u svetu, a i kod nas, primenjuje za kontrolu kemijske stabilnosti i prognoziranje veka upotrebljivosti baruta. Radi ocene pouzdanosti metode ispitivani su uzorci prirodno starenog jednobaznog baruta tipa NC i dvobaznog baruta tipa NGB različitih godina proizvodnje. Uzorci su uzimani iz ubojnih sredstava. Određene su konstante brzine reakcije utroška stabilizatora i vremena upotrebljivosti baruta. Ove vrednosti upoređene su sa analognim rezultatima dobijenim za iste barute pre dvadeset godina pri čemu je utvrđeno zadovoljavajuće slaganje kako za prirodno tako i ubrzano starenje. Pored toga, utvrđeno je da NC baruti iz dehermetizovanog pakovanja municije pokazuju znatno manju stabilnost od baruta iz originalnog pakovanja. / Monitoring the content of the stabilizer is one of the most reliable and modern methods used all over the world as well as in our country for chemical stability control and shelf life prediction of gun powders. For reliability rating of the used method, there has been examined samples of naturally aged single-based gun powder NC type and double-based gun powder NGB type all manufactured in different years. The samples were taken from explosive ordnance. Reaction rates constants of stabilizer consumption and shelf life of gun powders have been determined. These values were compared to analog results taken for the same gun powders tested 20 years ago. Satisfactory agreement either for naturally or accelerating aging gun powders has been confirmed. Beside that, it was determined that NC gun powder from non hermetic munitions cases proved to be considerably less stable than the originally packed NC gun powder.

Abstract licence: CC BY

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