Synthesis and determination of the absolute configuration of fudecalone
Hidenori Watanabe, Takahiro Yamaguchi, Takeshi Furuuchi and 3 more
ARKIVOC · 2003
doi:10.3998/ark.5550190.0004.826 (opens in a new tab)
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Abstract
We have synthesized the proposed structure of Fudecalone, but its NMR spectral data were not identical with those of the natural compound.Further investigations on the conformational isomerization and synthesis of a diastereomer show natural fudecalone to be a trans-fused octalone.The absolute configuration has been determined following the synthesis of both enantiomers.
Abstract licence: CC BY
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