Direct electrophilic N-trifluoromethylthiolation of amines with trifluoromethanesulfenamide
Sébastien Alazet, Kevin Ollivier, Thierry Billard
Beilstein Journal of Organic Chemistry · 2013
doi:10.3762/bjoc.9.270 (opens in a new tab)
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Abstract
The CF3SN moiety is a substituent with interesting properties. However, there is no easy synthetic access to molecules bearing this group. The trifluoromethanesulfenamide is a new reagent for the electrophilic trifluoromethylthiolation which reacts easily with amines to obtain trifluoromethylsulfanylamines with good yields.
Abstract licence: CC BY
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