Non-cross-linked polystyrene-supported 2-imidazolidinone chiral auxiliary: synthesis and application in asymmetric alkylation reactions
Quynh Pham Bao Nguyen, Taek Hyeon Kim
Beilstein Journal of Organic Chemistry · 2013
doi:10.3762/bjoc.9.248 (opens in a new tab)
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Abstract
Asymmetric alkylation reactions using non-cross-linked polystyrene (NCPS)-supported 2-imidazolidinone chiral auxiliaries were successfully investigated with excellent diastereocontrol (>99% de). The recovery and the recycling of this soluble polymer-supported chiral auxiliary were achieved in order to produce highly optical pure carboxylic acids.
Abstract licence: CC BY
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