Chemoselective reduction of aldehydes by ruthenium trichloride and resin-bound formates
Basudeb Basu, Bablee Mandal, Sajal Das and 2 more
Beilstein Journal of Organic Chemistry · 2008
doi:10.3762/bjoc.4.53 (opens in a new tab)
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Abstract
A simple, chemoselective transfer hydrogenation of aryl aldehydes with the aid of Amberlite® resin formate (ARF), a stable H-donor, in the presence of catalytic ruthenium trichloride is described. Aromatic aldehydes and 1,2-diketones are reduced efficiently and selectively, while aryl ketones remain unchanged. Several other potentially reducible groups attached to the aromatic moiety are unaffected.
Abstract licence: CC BY
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