Synthesis and investigation on optical and electrochemical properties of 2,4-diaryl-9-chloro-5,6,7,8-tetrahydroacridines
Najeh Tka, Mohamed Adnene Hadj Ayed, Mourad Ben Braiek and 2 more
Beilstein Journal of Organic Chemistry · 2021
doi:10.3762/bjoc.17.162 (opens in a new tab)
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Abstract
A facile synthesis of 2,4-diaryl-9-chloro-5,6,7,8-tetrahydroacridine derivatives is reported which is based on POCl3-mediated cyclodehydration followed by double Suzuki–Miyaura cross-coupling. The absorption and fluorescence properties of the obtained products were investigated and their HOMO/LUMO energy levels were estimated by cyclic voltammetry measurements. Besides, density functional theory calculations were carried out for further exploration of their electronic properties.
Abstract licence: CC BY
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