Selective bromochlorination of a homoallylic alcohol for the total synthesis of (−)-anverene
Frederick J. Seidl, Noah Z. Burns
Beilstein Journal of Organic Chemistry · 2016
doi:10.3762/bjoc.12.129 (opens in a new tab)
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Abstract
The scope of a recently reported method for the catalytic enantioselective bromochlorination of allylic alcohols is expanded to include a specific homoallylic alcohol. Critical factors for optimization of this reaction are highlighted. The utility of the product bromochloride is demonstrated by the first total synthesis of an antibacterial polyhalogenated monoterpene, (−)-anverene.
Abstract licence: CC BY
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