Metal-free one-pot synthesis of 2-substituted and 2,3-disubstituted morpholines from aziridines
Hongnan Sun, Binbin Huang, Run Lin and 2 more
Beilstein Journal of Organic Chemistry · 2015
doi:10.3762/bjoc.11.59 (opens in a new tab)
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Abstract
The metal-free synthesis of 2-substituted and 2,3-disubstituted morpholines through a one-pot strategy is described. A simple and inexpensive ammonium persulfate salt enables the reaction of aziridines with halogenated alcohols to proceed via an SN2-type ring opening followed by cyclization of the resulting haloalkoxy amine.
Abstract licence: CC BY
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