3α,5α-Cyclocholestan-6β-yl ethers as donors of the cholesterol moiety for the electrochemical synthesis of cholesterol glycoconjugates
Aneta M. Tomkiel, Adam Biedrzycki, Jolanta Płoszyńska and 3 more
Beilstein Journal of Organic Chemistry · 2015
doi:10.3762/bjoc.11.16 (opens in a new tab)
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Abstract
3α,5α-Cyclocholestan-6β-yl alkyl and aryl ethers were proved to be efficient cholesteryl donors in the electrochemical synthesis of glycoconjugates. 3α,5α-Cyclocholestan-6β-ol (i-cholesterol) and its tert-butyldimethylsilyl ether can also be used for this purpose. The i-cholesterol derivatives show similar reactivities to those of previously studied 3α,5α-cyclocholestan-6β-thioethers.
Abstract licence: CC BY
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