Zirconoarylation of alkynes through p-chloranil-promoted reductive elimination of arylzirconates
Xiaoyu Yan, Chao Chen, Chanjuan Xi
Beilstein Journal of Organic Chemistry · 2014
doi:10.3762/bjoc.10.48 (opens in a new tab)
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Abstract
A novel method for the zirconoarylation of alkynes was developed. TCQ-promoted reductive elimination of arylzirconate [LiCp2ZrAr(RC≡CR)], which was prepared by the reaction of zirconocene–alkyne complexes with aryllithium compounds, afforded trisubstituted alkenylzirconocenes. This reaction can afford multi-substituted olefins with high stereoselectivity.
Abstract licence: CC BY
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