C–H-Functionalization logic guides the synthesis of a carbacyclopamine analog
Sebastian Rabe, Johann Moschner, Marina Bantzi and 2 more
Beilstein Journal of Organic Chemistry · 2014
doi:10.3762/bjoc.10.161 (opens in a new tab)
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Abstract
The chemical synthesis of carbacyclopamine analog 2, a cyclopamine analog with an all-carbon E-ring, is reported. The use of C–H-functionalization logic and further metal-catalyzed transformations allows for a concise entry to this new class of acid-stable cyclopamine analogs.
Abstract licence: CC BY
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