Synthesis of the B-seco limonoid core scaffold
Hanna Bruss, Hannah Schuster, Rémi Martinez and 3 more
Beilstein Journal of Organic Chemistry · 2014
doi:10.3762/bjoc.10.15 (opens in a new tab)
We email you when a new notice or a question about this paper appears.
Abstract
Synthetic investigations towards the structurally complex and highly decorated framework of B-seco limonoid natural products by means of a [3,3]-sigmatropic rearrangement are described. Detailed model studies reveal, that an Ireland–Claisen rearrangement can be employed to construct the central C9–C10 bond thereby giving access to the B-seco limonoid scaffold. However, application of the developed strategy ended up failing in more complex and sterically demanding systems.
Abstract licence: CC BY
Reads
Read by people on this page
None yet.
Checked or read by AI through naulon
None yet.
A person counts once a day per paper. We keep no cookie and no address: a reader is a hash that changes every day. Any month under five reads shows no number.
Are you an author?
Is this your paper?
Claim it to add your note and be paid when agents cite it. Free.