Fast Procedures for the Electrodeposition of Platinum Nanostructures on Miniaturized Electrodes for Improved Ion Sensing

Nanostructured materials have attracted considerable interest over the last few decades to enhance sensing capabilities thanks to their unique properties and large surface area. In particular, noble metal nanostructures offer several advantages including high stability, non-toxicity and excellent electrochemical behaviour. However, in recent years the great expansion of point-of-care (POC) and wearable systems and the attempt to perform measurements in tiny spaces have also risen the need of increasing sensors miniaturization. Fast constant potential electrodeposition techniques have been proven to be an efficient way to obtain conformal platinum and gold nanostructured layers on macro-electrodes. However, this technique is not effective on micro-electrodes. In this paper, we investigate an alternative one-step deposition technique of platinum nanoflowers on micro-electrodes by linear sweep voltammetry (LSV). The effective deposition of platinum nanoflowers with similar properties to the ones deposited on macro-electrodes is confirmed by morphological analysis and by the similar roughness factor (~200) and capacitance (~18 <inline-formula> <math display="inline"> <semantics> <mi mathvariant="sans-serif">&#956;</mi> </semantics> </math> </inline-formula>F/mm<inline-formula> <math display="inline"> <semantics> <msup> <mrow></mrow> <mn>2</mn> </msup> </semantics> </math> </inline-formula>). The electrochemical behaviour of the nanostructured layer is then tested in an solid-contact (SC) <inline-formula> <math display="inline"> <semantics> <mrow> <mi>L</mi> <msup> <mi>i</mi> <mo>+</mo> </msup> </mrow> </semantics> </math> </inline-formula>-selective micro-electrode and compared to the case of macro-electrodes. The sensor offers Nernstian calibration with same response time (~15 s) and a one-order of magnitude smaller limit of detection (LOD) (<inline-formula> <math display="inline"> <semantics> <mrow> <mn>2.6</mn> <mo>&#215;</mo> <msup> <mn>10</mn> <mrow> <mo>&#8722;</mo> <mn>6</mn> </mrow> </msup> </mrow> </semantics> </math> </inline-formula>) with respect to the macro-ion-selective sensors (ISE). Finally, sensor reversibility and stability in both wet and dry conditions is proven.

Abstract licence: CC BY

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