Aqueous-Based Binary Sulfide Nanoparticle Inks for Cu 2 ZnSnS 4 Thin Films Stabilized with Tin(IV) Chalcogenide Complexes

Cu₂ZnSnS₄ (CZTS) is a promising semiconductor material for photovoltaic applications, with excellent optical and electronic properties while boasting a nontoxic, inexpensive, and abundant elemental composition. Previous high-quality CZTS thin films often required either vacuum-based deposition processes or the use of organic ligands/solvents for ink formulation, which are associated with various issues regarding performance or economic feasibility. To address these issues, an alternative method for depositing CZTS thin films using an aqueous-based nanoparticle suspension is demonstrated in this work. Nanoparticles of constituent binary sulfides (Cu_xS and ZnS) are stabilized in an ink using tin(IV)-based, metal chalcogenide complexes such as [Sn₂S₆]^4−. This research paper provides a systematic study of the nanoparticle synthesis and ink formulation via the enabling role of the tin chalcogenide complexing power, the deposition of high-quality CZTS thin films via spin coating and annealing under sulfur vapor atmosphere, their structural characterization in terms of nanocrystal phase, morphology, microstructure, and densification, and their resultant optoelectronic properties.

Abstract licence: CC BY

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