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Acid Catalyzed Formation of C–C and C–S Bonds via Excited State Proton Transfer

Alessandro Strada, Mattia Fredditori, Giuseppe Zanoni and 1 more

Molecules · 2019

doi:10.3390/molecules24071318 (opens in a new tab)

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Abstract

The behavior of 2-naphthol and 7-bromo-2-naphthol as organic photoacids are exploited in organic synthesis for the preparation of benzyl sulfides (using a trichloroacetimidate derivative as the starting substrate) and polycyclic amines via acid catalyzed condensation of 1,2,3,4-tetrahydroisoquinoline with aldehydes.

Abstract licence: CC BY

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