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Isolation of a Cyclic (Alkyl)(amino)germylene

Liliang Wang, Yi Shan Lim, Yongxin Li and 2 more

Molecules · 2016

doi:10.3390/molecules21080990 (opens in a new tab)

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Abstract

A 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC3N five-membered ring skeleton. By reducing 2 with KC8, cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with TEMPO, N2O and S8, producing the 1:2 adduct 4, the oxo-bridged dimer 5 and the sulfido-bridged dimer 6, respectively.

Abstract licence: CC BY

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