Scandium Doping Effect on a Layered Perovskite Cathode for Low-Temperature Solid Oxide Fuel Cells (LT-SOFCs)

Layered perovskite oxides are considered as promising cathode materials for the solid oxide fuel cell (SOFC) due to their high electronic/ionic conductivity and fast oxygen kinetics at low temperature. Many researchers have focused on further improving the electrochemical performance of the layered perovskite material by doping various metal ions into the B-site. Herein, we report that Sc³⁺ doping into the layered perovskite material, PrBaCo₂O_{5+<i>&#948;</i>} (PBCO), shows a positive effect of increasing electrochemical performances. We confirmed that Sc³⁺ doping could provide a favorable crystalline structure of layered perovskite for oxygen ion transfer in the lattice with improved Goldschmidt tolerance factor and specific free volume. Consequently, the Sc³⁺ doped PBCO exhibits a maximum power density of 0.73 W cm^&#8722;2 at 500 &#176;C, 1.3 times higher than that of PBCO. These results indicate that Sc³⁺ doping could effectively improve the electrochemical properties of the layered perovskite material, PBCO.

Abstract licence: CC BY

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