Regioselectivity of Arylation of 2,3’-Biquinolyl Dianion
Yu. I. Smushkevich, I. V. Borovlev, I. V. Aksenova and 1 more
Molecules · 1999
doi:10.3390/40500126 (opens in a new tab)
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Abstract
The dianion of 2,3’-biquinolyl with aryl- and hetaryl halides forms the products of arylation to 4’-position, which on treatment with alkyl halides or water yield 1’-alkyl-1’,4’dihydro-2,3’-biquinolyls or 4’-aryl-1’,4’-dihydro-2,3’-biquinolyls respectively. The oxidation of the latter leads to 4’-aryl-2,3’-biquinolyls. The cation dependence of the arylation is shown.
Abstract licence: CC BY
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