Oxidative Degradations of the Side Chain of Unsaturated Ent-labdanes. Part I.
Karen Catalán MarÃÂn, Claudio Gallardo Araya, Mauricio Cuellar Fritis and 2 more
Molecules · 2007
doi:10.3390/12030318 (opens in a new tab)
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Abstract
A selective route for the degradation of the unsaturated side chain of ent-labdanes has been devised, giving two useful synthons: 2β-acetoxy-14,15,17-trinor-ent-labdane-8,13- dione (5) and 2β-acetoxy-14,15-dinor-ent-labd-8(17)-en-13-one (7), the use of which for the preparation of terpenylquinone derivatives shall be reported elsewhere.
Abstract licence: CC BY
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