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A Convenient Synthetic Route to Partial-Cone p-Carboxylatocalix[4]arenes

Robyn E. Fairbairn, Simon J. Teat, Kevin J. Gagnon and 1 more

CHIMIA · 2015

doi:10.2533/chimia.2015.516 (opens in a new tab)

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Abstract

p-Carboxylatocalix[n]arenes have emerged as useful building blocks for the construction of a diverse range of supramolecular assemblies. A convenient route to a p-carboxylatocalix[4]arene that is locked in a partial-cone conformation is presented. The conformation gives the molecule markedly different topological directionality relative to those previously used in self- and metal-directed assembly studies.

Abstract licence: CC BY-NC

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