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Synthesis and Reactivity of Zn–Biphenyl Metal–Organic Frameworks, Introducing a Diphenylphosphino Functional Group

Marco Ranocchiari, Jeroen Anton van Bokhoven

CHIMIA · 2013

doi:10.2533/chimia.2013.397 (opens in a new tab)

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Abstract

Structural features, synthesis, and reactivity of Zn–biphenyl metal–organic frameworks with MOF-5 topology are presented to show the chemical flexibility of such materials and to demonstrate the challenges that can be encountered and solved to avoid interpenetration. We introduce the synthesis of a Zn–biphenyl MOF with diphenylphosphino functionalization and illustrate its structural and chemical properties.

Abstract licence: CC BY-NC

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