Peptide-catalyzed 1,4-Addition Reactions of Aldehydes to Nitroolefins
Robert Kastl, Yukihiro Arakawa, Jörg Duschmalé and 2 more
CHIMIA · 2013
doi:10.2533/chimia.2013.279 (opens in a new tab)
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Abstract
Conjugate addition reactions of aldehydes to nitroolefins provide synthetically useful ?-nitroaldehydes. Here we summarize our research on peptide-catalyzed conjugate addition reactions of aldehydes to differently substituted nitroolefins. We show that peptides of the general type Pro-Pro-Xaa (Xaa = acidic amino acid) are not only highly active, robust and stereoselective catalysts but have also remarkable chemoselectivities.
Abstract licence: CC BY-NC
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