On applicability of Gibbs thermodynamics to nanoparticles
Samsonov V., Bazulev A., Sdobnyakov N.
Open Physics · 2003
doi:10.2478/bf02475858 (opens in a new tab)
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Abstract
The problem of applicability of thermodynamics to small objects has been investigated. It is shown that the Gibbs surface phase method may be extended to nanoparticles if the effective surface tension (the specific excess free energy) is interpreted as a function of the particle radius.
Abstract licence: CC BY-NC-ND
References26
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