Tetrabutylammonium fluorochromate(VI)(TBFAC): A mild and efficient reagent for oxidation of organic substrates
Ghammami Shahriare, Sajadi Seyed Abolfazl Seyed
Journal of the Serbian Chemical Society · 2005
doi:10.2298/jsc0511243g (opens in a new tab)
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Abstract
Orange solid tetrabutylammonium fluorochromate, (C4H9)4NCrO3F, TBAFC, is easily synthesized by the reaction of tetrabutylammonium fluoride with CrO3 in a 1:1 mole ratio. Tetrabutylammonium fluorochromate(VI) is a versatile reagent for the effective and selective oxidation of organic substrates, in particular of alcohols, under mild conditions. The facile oxidation of triphenylphosphine to triphenylphosphine oxide by TBAFC in CH3CN provides clear evidence for an oxygen-transfer reaction..
Abstract licence: CC BY
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