Thiocyanatochrome complexes in analytical chemistry: Determination of osmium(III)

New complex combinations of Os(III) complexed with thiourea and ethyl thiourea, as well as of complex anions of Cr(III) analogues of Reineke?s salt, [Cr(CNS)4(amine)2]-, where the amine is aniline, benzylamine morpholine etc., were synthesized. New gravimetric, oxidimetric and spectrophotometric analytical methods are proposed for the determination of Os(III). The experimental data were statistically processed and are not affected by systematic errors.

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