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Crystal structure of dimethylammonium tribromoplumbate(II), (CH3)2NH2PbBr3

Geselle M., Fuess H.

Zeitschrift für Kristallographie - New Crystal Structures · 1997

doi:10.1524/ncrs.1997.212.jg.234 (opens in a new tab)

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Abstract

Source of material: Crystals where grown from a solution of lead(II)acetate trihydrate and methylammonium bromide in the molar ratio 1:4 in concentrated hot hydrobromic acid.The tide compound is a metal-organic analogon of the high-BaMn03 structure.The anionic substructure consists of dimeric units of face-sharing PbBre octahedra which in turn share the free comers to form a three-dimensional network.The cation shows isotropic orientational disorder which makes satisfactory localization of the C and Ν atoms impossible.

Abstract licence: CC BY-NC-ND

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