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THE MOLECULAR STRUCTURE OF [(C5H3NMeNH 2)2Li( μ-Br) 2Li[(C 5H3NMeNH 2)2], (C 5H3NMeNH 2 = 6-methyl-2-aminopyridine)

Jones, Cameron, Junk, Peter C., Smithies, Neil A.

Main Group Metal Chemistry · 2001

doi:10.1515/mgmc.2001.24.11.801 (opens in a new tab)

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Abstract

au> Figure 1.Molecular structure of [(C 5 H 3 NMeNH 2 ) 2 Li(µ-Br) 2 Li[(C 5 H 3 MeNH 2 ) 2 ].Selected bond lengths (Å) and angles ( o ): Li1-Br1 2.614(5), Li1-Br1#1 2.616(5), Li1-N1 2.116(5), Li1-N3 2.100(5), Li1...Li1#1 3.544(5), Br1...Br1#1 3.846(5), H2NA-Br1 2.54(5), H4A-Br1#1 2.65(5), H4B-Br1#2 2.76(5), N2-Br1 3.469(3), N4-Br1#1 3.504(2), N4-Br1#2 3.632(2), N1-Li1-Br1 119.20(19),N3-Li1-Br1 105.65(19),N1-Li1-Br1#1 103.90(19),N3-Li1-Br1#1 119.98(19),N1-Li1-N3 112.9(2),Li1-Br1-Li1#1 85.32(15), Br1-Li1-Br1#1 94.68(15).Symmetry transformations used to generate equivalent atoms: #1 -x+1,-y+2,-z+2, #2 x+1,y,z

Abstract licence: CC BY

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