A new cadmium(ii) coordination polymer with 1,4-cyclohexanedicarboxylate acid and phenanthroline derivate: Synthesis and crystal structure

A new Cd( ii ) coordination polymers, formulated as [Cd(1,4-chdc)(L)] n ( 1 ) (L = 1-(1 H -imidazo[4,5- f ][1,10]phenanthrolin-2-yl)naphthalen-2-ol ligands and 1,4-H 2 chdc = 1,4-cyclohexanedicarboxylate acid), were successfully synthesized by using L ligand and 1,4-H 2 chdc acid under hydrothermal conditions and characterized by single crystal X-ray elemental analyses, diffraction, and IR spectroscopy. Each Cd( ii ) atom is a distorted pentagonal bipyramidal geometry connecting the deprotonated 1,4-chdc anion to form a 2D layer, and a 2D layer is formed into a 3D supramolecular structure by the π–π stacking interactions between neighboring layers.

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   Crystal structure refinement with SHELXL · 2015

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