Synthesis of the Benzo-fused Indolizidine Alkaloid Mimics
Daniel L. Comins, Kazuhiro Higuchi
Beilstein Journal of Organic Chemistry · 2007
doi:10.1186/1860-5397-3-42 (opens in a new tab)
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Abstract
A general synthesis of various benzo-fused indolizidine alkaloid mimics has been developed. The indolizidine derivatives 8 were prepared via heteroaryl Grignard addition to N-acylpyridinium salts followed by an intramolecular Heck cyclization. Further substitution reactions were developed to demonstrate that heterocycles 8 are good scaffolds for chemical library preparation.
Abstract licence: CC BY
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