TlPO3 and its comparison with isotypic RbPO3 and CsPO3
Matthias Weil
Acta Crystallographica Section E: Crystallographic Communications · 2020
doi:10.1107/s2056989020011238 (opens in a new tab)
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Abstract
The crystal structure of thallium(I) catena-polyphosphate, TlPO3, contains a polyphosphate chain extending parallel to [010] with a repeating unit of two phosphate tetrahedra. The TlI atom is located in-between the polyphosphate chains and is bonded by oxygen atoms in a distorted [6 + 1] coordination in the form of a monocapped prism, with the longest Tl—O bond to the bridging O atom of the polyphosphate chain. A quantitative structural comparison with isotypic RbPO3 and CsPO3 reveals that the usually pronounced stereoactivity of the 6s2 lone pair at the TlI atom is not apparent in the case of TlPO3.
Abstract licence: CC BY
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