Crystal structure of di-μ-chlorido-bis[dichlorido(l-histidinium-κO)cadmium(II)]
Nacira Mohamedi, Slim Elleuch, Sihem Boufas and 2 more
Acta Crystallographica Section E: Crystallographic Communications · 2019
doi:10.1107/s205698901900690x (opens in a new tab)
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Abstract
In the title compound, [Cd 2 (C 6 H 9 N 3 O 2 ) 2 Cl 6 ], the coordination polyhedra around the Cd II cations are distorted trigonal bipyramids. Two of the chloride ions (one axial and one equatorial) are bridging to the other metal atom, leading to a Cd...Cd separation of 3.9162 (4) Å. The O atom of the L-histidinium cation lies in an axial site. In the crystal, numerous N—H...Cl, N—H...O, C—H...O and C—H...Cl hydrogen bonds link the molecules into a three-dimensional network. Theoretical calculations and spectroscopic data are available as supporting information.
Abstract licence: CC BY
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