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Crystal structure of triethyl 2-(5-nitro-2H-indazol-2-yl)propane-1,2,3-tricarboxylate

Mohammed Boulhaoua, Mohammed Benchidmi, El Mokhtar Essassi and 2 more

Acta Crystallographica Section E: Crystallographic Communications · 2015

doi:10.1107/s2056989015017235 (opens in a new tab)

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Abstract

In the title compound, C19H23N3O8, the 5-nitro-2H-indazol-2-yl unit is almost planar, with the maximum deviation from the mean plane being 0.024 (2) Å. The fused-ring system is nearly perpendicular to the three carboxylate groups, with dihedral angles of 90.0 (3), 83.8 (1) and 80.4 (1)°. The ethyl groups attached to both ends of the propane chain are each disordered over two sets of sites, with site-occupancy ratios of 0.425 (17):0.575 (17) and 0.302 (15):0.698 (15). In the crystal, molecules are linked by pairs of C—H...N hydrogen bonds, forming inversion dimers. The dimers are further linked by C—H...O hydrogen bonds, forming a three-dimensional network.

Abstract licence: CC BY

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