Crystal structure of bis{S-hexyl 3-[4-(dimethylamino)benzylidene]dithiocarbazato-κ2N3,S}copper(II)
E. Zangrando, M. S. Begum, R. Miyatake and 2 more
Acta Crystallographica Section E: Crystallographic Communications · 2015
doi:10.1107/s2056989015009342 (opens in a new tab)
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Abstract
In the title complex, [Cu(C16H24N3S2)2], the CuII atom is coordinated by two azomethine N and two thiolate S atoms of the chelating Schiff base ligands, resulting in a distorted square-planar coordination environment. The S—Cu—N chelating angle is of 84.41 (5)°. The CuII atom is located on a crystallographic inversion centre, leading to a trans configuration of the N,S-chelating ligands.
Abstract licence: CC BY
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