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2-N-Benzyl-2,6-dideoxy-2,6-imino-3,4-O-isopropylidene-d-allononitrile

Amber L. Thompson, George W. J. Fleet, Sarah F. Jenkinson and 1 more

Acta Crystallographica Section E · 2013

doi:10.1107/s1600536813030584 (opens in a new tab)

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Abstract

X-ray crystallography firmly established the relative stereochemistry of the title compound, C 16 H 20 N 2 O 3 . The acetonide ring adopts an envelope conformation with one of the O atoms as the flap and the piperidine ring adopts a slightly twisted boat conformation. The absolute configuration was determined by use of D-ribose as the starting material. The compound exists as O—H...O hydrogen-bonded chains of molecules running parallel to the b axis.

Abstract licence: CC BY

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