Poly[μ-aqua-μ5-[2-(2,3,6-trichlorophenyl)acetato]-caesium]

In the structure of the title complex, [Cs(C 8 H 4 Cl 3 O 2 )(H 2 O)] n , the caesium salt of the commercial herbicide fenac [(2,3,6-trichlorophenyl)acetic acid], the irregular eight-coordination about Cs + comprises a bidentate O:Cl -chelate interaction involving a carboxylate-O atom and an ortho -related ring-substituted Cl atom, which is also bridging, a triple-bridging carboxylate-O atom and a bridging water molecule. A two-dimensional polymer is generated, lying parallel to (100), within which there are water–carboxylate O—H...O hydrogen-bonding interactions.

Abstract licence: CC BY

1. 5.

   Structure validation in chemical crystallography · 2009

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