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(2E)-3-(2-Chloro-7-methylquinolin-3-yl)-1-(6-chloro-2-methyl-4-phenylquinolin-3-yl)prop-2-en-1-one ethanol monosolvate

R. Prasath, S. Sarveswari, Seik Weng Ng and 1 more

Acta Crystallographica Section E · 2013

doi:10.1107/s1600536813022022 (opens in a new tab)

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Abstract

In the title ethanol solvate, C29H20Cl2N2O·C2H5OH, the quinolinyl residues form a dihedral angle of 46.41 (4)° with each other, and each is inclined [Cp—C—C=O and C=C—C—Cp (p = pyridyl) torsion angles = 54.8 (2) and 144.44 (19)°, respectively] with respect to the almost planar bridging prop-2-en-1-one residue [O=C—C=C torsion angle = −4.1 (3)°]. The ethanol solvent molecule is disordered over two positions of equal occupancy and is located close to a centre of inversion. These molecules reside in cavities defined by the organic molecules, which are connected into a three-dimensional architecture by C—H...Cl, C—H...O and C—H...N interactions, as well as π–π contacts [inter-centroid distances = 3.5853 (10) and 3.8268 (11) Å], each involving pyridyl rings.

Abstract licence: CC BY

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