[(R)-2,2-Bis(diphenylphosphanyl)-1,1′-binaphthyl-κ2P,P′]{2-[(2R)-1,2-diamino-1-(4-methoxyphenyl)-3-methylbutyl]-5-methoxyphenyl-κC1}hydridoruthenium(II) benzene monosolvate
Kamaluddin Abdur-Rashid, Alan J. Lough
Acta Crystallographica Section E · 2012
doi:10.1107/s1600536812046065 (opens in a new tab)
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Abstract
In the title complex, [Ru(C19H25N2O2)H(C44H32P2)]·C6H6, the RuII ion is in a distorted octahedral coordination environment with the hydride H atom trans to the tertiary carbinamine N atom, giving an H—Ru—N angle of 160.8 (12)°. The equatorial sites are occupied by two P atoms, the secondary carbinamine N atom and a coordinated C atom.
Abstract licence: CC BY
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