Poly[aqua-μ-bromido-(μ2-5-methylpyrazine-2-carboxylato-κ4N1,O2:O2,O2′)lead(II)]
Pan Yang, Yan Liu, Hua Yun Li and 1 more
Acta Crystallographica Section E · 2012
doi:10.1107/s1600536812033776 (opens in a new tab)
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Abstract
In the title coordination polymer, [PbBr(C6H5N2O2)(H2O)]n, the PbII atom is coordinated by one pyrazine N atom, two bridging Br atoms, a water molecule and three carboxylate O atoms. Bridging by the two anions generates a layer structure parallel to (001); the layers are linked by O—H...N and O—H...Br hydrogen bonds, forming a three-dimensional network. The lone pair is stereochemically active, resulting in a Ψ-dodecahedral coordination environment for PbII.
Abstract licence: CC BY
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