(2E,6E)-2,6-Bis(ferrocenylmethylidene)cyclohexanone dichloromethane monosolvate
Shi-Jia Long, Wu Yang, Yong-Hong Liu
Acta Crystallographica Section E · 2012
doi:10.1107/s1600536812030899 (opens in a new tab)
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Abstract
In the title compound, [Fe2(C5H5)2(C18H16O)]·CH2Cl2, the C=C bonds both adopt E conformations. In one ferrocenyl group, the five-membered rings are in a near-eclipsed conformation, whereas in the other they are mutually rotated by ca 21.5°. The central cyclohexanone ring adopts a sofa conformation. In the crystal, the dichloromethane solvent moleucle forms C—H...O hydrogen bonds to the organometallic molecules to generate [010] chains of alternating solvent and organometallic species.
Abstract licence: CC BY
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