μ-2,2′-Bipyrimidine-κ4N1,N1′:N3,N3′-bis[iodido(triphenylphosphane-κP)copper(I)] dimethylformamide disolvate
Mohammed Fettouhi
Acta Crystallographica Section E · 2012
doi:10.1107/s1600536812028139 (opens in a new tab)
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Abstract
In the title binuclear centrosymmetric complex, [Cu2I2(C8H6N4)(C18H15P)2]·2C3H7NO, the bis-bidentate 2,2′-bipyrimidine ligand bridges two copper(I) ions, each additionally bound to an iodide anion and a triphenylphosphane ligand in a distorted tetrahedral N2IP geometry. The complex molecules pack in columns parallel to [100] generating cavities occupied by dimethylformamide solvent molecules. Weak C—H...I hydrogen-bonding interactions help to stabilize the crystal packing.
Abstract licence: CC BY
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