Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ2O1,N,N′,O1′}cobalt(III) dimethylformamide monosolvate
Yun Wei, Ting Pang, Jiacheng Liu and 2 more
Acta Crystallographica Section E · 2012
doi:10.1107/s1600536812011324 (opens in a new tab)
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Abstract
In the title compound, [Co(C 18 H 18 N 2 O 4 )Cl(H 2 O)]·C 3 H 7 NO, the Co III ion is six-coordinated by a tetradentate 6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolate ligand, with a chloride ion and an aqua ligand in the apical positions. The compound crystallized as a dimethylformamide (DMF) monosolvate. In the crystal, complex molecules are linked via O—H water ...O hydrogen bonds to form a dimer-like arrangement. These dimers are linked via a C—H...Cl interaction, and the DMF molecule is linked to the complex molecule by C—H...O interactions.
Abstract licence: CC BY
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