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catena-Poly[[[2-({6-[(pyrimidin-2-ylsulfanyl-κS)methyl]pyridin-2-yl-κN}methylsulfanyl)pyrimidine]copper(I)]-μ-thiocyanato-κ2N:S]

Rong Peng, Seik Weng Ng

Acta Crystallographica Section E · 2012

doi:10.1107/s160053681201063x (opens in a new tab)

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Abstract

The N -heterocyclic ligand in the title compound, [Cu(NCS)(C 15 H 13 N 5 S 2 )] n , coordinates to the Cu I atom through its pyridine N-donor site, and adjacent metal atoms are bridged by the thiocyanate ion, forming a helical chain along the b axis. The geometry of the metal atom is tetrahedral owing to a somewhat long intramolecular Cu—S interaction of 2.5621 (9) Å.

Abstract licence: CC BY

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