N′-[(1E,2E)-3,7-Dimethylocta-2,6-dien-1-ylidene]pyridine-4-carbohydrazide
Mashooq A. Bhat, Hatem A. Abdel-Aziz, Hazem A. Ghabbour and 2 more
Acta Crystallographica Section E · 2012
doi:10.1107/s1600536812009075 (opens in a new tab)
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Abstract
In the title compound, C16H21N3O, the molecule adopts an E conformation about the central C=N double bond. The 2-methylpent-2-ene group is disordered over two sets of sites, with a refined occupancy ratio of 0.785 (8):0.215 (8). The dihedral angle between the essentially planar [the r.m.s. value for the major component is 0.021 (7) and its maximum deviation is 0.025 (4) Å; the r.m.s. value for the minor component is 0.03 (4) and its maximum deviation is 0.05 (3) Å] major and minor components of the 2-methylbut-2-ene group is 35.9 (13)°. In the crystal, C—H...O and N—H...O hydrogen bonds link the molecules, with the same O atom acting as the acceptor. This results in C11(4) and C11(5) [001] chains.
Abstract licence: CC BY
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