{S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate
Karen A. Crouse, Thahira B. S. A. Ravoof, Mohamed Ibrahim Mohamed Tahir and 1 more
Acta Crystallographica Section E · 2012
doi:10.1107/s1600536812006952 (opens in a new tab)
We email you when a new notice or a question about this paper appears.
Abstract
The structure of the title compound, [Ni(C15H14N3S2)2]·H2O, has one molecule in the asymmetric unit, along with a solvent water molecule. The two different Schiff base moieties coordinate to the central NiII ion as tridentate N,N′,S-chelating ligands, creating a six-coordinate distorted octahedral environment [the smallest angle being 77.43 (7)° and the widest angle being 169.99 (7)°]. The mean planes of the two ligands are nearly orthogonal to each other with an angle of 89.53 (6)°. The packing of the complex is supported by O—H...N and O—H...S hydrogen bonding between the solvent water molecule and the uncoordinated N and S atoms of neighbouring ligands.
Abstract licence: CC BY
Reads
Read by people on this page
None yet.
Checked or read by AI through naulon
None yet.
A person counts once a day per paper. We keep no cookie and no address: a reader is a hash that changes every day. Any month under five reads shows no number.
Are you an author?
Is this your paper?
Claim it to add your note and be paid when agents cite it. Free.