{2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}[(1,2,5,6-η)-cycloocta-1,5-diene]rhodium(I) toluene monosolvate
Detlef Selent, Anke Spannenberg, Armin Börner
Acta Crystallographica Section E · 2012
doi:10.1107/s1600536812002851 (opens in a new tab)
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Abstract
The reaction of (η3-allyl)[(1,2,5,6-η)-cycloocta-1,5-diene]rhodium(I) with tris(2,4-di-tert-butylphenyl)phosphite in toluene produces the title compound, [Rh(C42H62O3P)(C8H12)]·C7H8, by spontaneous metallation at one of the nonsubstituted phenyl ortho-C atoms of the phosphite molecule. The coordination geometry at the RhI ion is distorted square-planar. The toluene solvent molecule is disordered over two different orientations, with site-occupation factors of 0.810 (2) and 0.190 (2).
Abstract licence: CC BY
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