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(2E,6E)-2,6-Bis(4-methylbenzylidene)cyclohex-3-en-1-one

M. Saeed Abaee, Werner Massa, Mohammad M. Mojtahedi and 1 more

Acta Crystallographica Section E · 2012

doi:10.1107/s1600536811055632 (opens in a new tab)

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Abstract

The title compound, C22H20O, shows an approximately planar cyclohexenone ring [maximum deviation = 0.069 (4) Å], with a disordered position of the C=C bond [ratio = 0.71 (2)/0.29 (2)]. The benzene rings of the 4-methylbenzylidene units, attached in the 2- and 6-positions to the cyclohexenone ring, are rotated in the same direction by 28.6 (4) and 22.4 (4)°, with respect to the mean plane of the cyclohexenone ring [fraction 0.71 (2); maximum deviation = 0.06 (3) Å]. In the crystal, molecules are packed in the manner of a distorted hexagonal rod packing with their long axes all aligned along [201]. A number of C—H...π interactions stablize the crystal structure.

Abstract licence: CC BY

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