1-(2,4-Dichlorobenzyl)pyridinium bis(2-sulfanylidene-1,3-dithiole-4,5-dithiolato-κ2S,S′)nickelate(III)
Guang-Xiang Liu
Acta Crystallographica Section E · 2011
doi:10.1107/s1600536811045004 (opens in a new tab)
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Abstract
In the title compound, (C12H10Cl2N)[Ni(C3S5)2], the NiIII atom is chelated by two bidentate 2-sulfanylidene-1,3-dithiole-4,5-dithiolate (dmit) dianions and shows a distorted square-planar geometry. The two dmit ligands are twisted with respect to each other by 3.21 (2)°. In the cation, the two aromatic groups linked by the methylene bridging group form a dihedral angle of 68.09 (2)°. S...S [3.6212 (11) and 3.5573 (9) Å] and Ni...S [3.566 (2)Å] interactions influence the arrangement of the anions in the crystal.
Abstract licence: CC BY
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