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6-Bromo-3-{2-[2-(diphenylmethylene)hydrazinyl]-1,3-thiazol-5-yl}-2H-chromen-2-one chloroform monosolvate

Afsheen Arshad, Hasnah Osman, Chan Kit Lam and 2 more

Acta Crystallographica Section E · 2011

doi:10.1107/s1600536811012335 (opens in a new tab)

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Abstract

In the title compound, C25H16BrN3O2S·CHCl3, the thiazole ring is approximately planar [maximum deviation = 0.002 (3) Å] and makes dihedral angles of 10.75 (14) and 87.75 (15)/2.80 (14)° with the pyran ring system and the two terminal phenyl rings, respectively. The solvent molecule is disordered over two sets of sites, with refined occupancies of 0.639 (7) and 0.361 (7). In the crystal, molecules are connected via pairs of weak C—H...O interactions, forming centrosymmetric dimers. An intramolecular C—H...O hydrogen bond generates an S(6) ring motif.

Abstract licence: CC BY

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