catena-Poly[[{N,N-dimethyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ3N,N′,N′′}(thiocyanato-κN)cadmium]-μ-thiocyanato-κ2S:N]
Nura Suleiman Gwaram, Hamid Khaledi, Hapipah Mohd Ali
Acta Crystallographica Section E · 2011
doi:10.1107/s1600536811010063 (opens in a new tab)
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Abstract
In the title compound, [Cd(NCS)2(C11H17N3)]n, the CdII atom is octahedrally coordinated by the N,N′,N′′-tridentate Schiff base ligand and one terminal thiocyanate N atom. Two trans-N:S-bridging thiocyanates complete the N5S donor set around the Cd atom. In the crystal, adjacent CdII ions are linked by the thiocyanate N:S-bridges into polymeric chains along the c axis.
Abstract licence: CC BY
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